Ionic liquids with metal chelate anions.
نویسندگان
چکیده
A series of stable (air, water stable and with good thermal stability) and hydrophobic ionic liquids based upon metal chelate anions were synthesized, which were shown to be effective, mild, and easy to recycle catalysts at the same time stable solvents for the oxidation of cyclohexene.
منابع مشابه
Extraction behavior of divalent metal cations in ionic liquid chelate extraction systems using 1-alkyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imides and thenoyltrifluoroacetone.
The extraction behavior of several divalent metal cations (M(2+)) in ionic liquid chelate extraction systems was investigated using several 1-alkyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ionic liquids ([Rmim][Tf(2)N]) as extraction solvent and thenoyltrifluoroacetone (Htta) as extractant. The behavior was compared with that using less hydrophobic 1-alkyl-3-methylimidazolium hexa...
متن کاملChelate Extraction of Metals into Ionic Liquids
In the solvent extraction of metal cations into ionic liquids, use of Brønsted acid-type chelate extractants has some advantages including simplicity in controlling extraction selectivity by selecting suitable aqueous phase pH values and simple back-extraction recovery of the extracted metals using acid solutions. In this review, various fundamental and applied research on metal extraction usin...
متن کاملIonic liquids from cationic palladium(II) chelate complexes: preparation, thermal properties, and crystal structures.
Metal-containing ionic liquids comprising cationic Pd(II) chelate complexes and the bis(trifluoromethanesulfonyl)amide (Tf2N) anion were prepared: [Pd(acac)(Me4en)]Tf2N (1), [Pd(acac)(BuMe3en)]Tf2N (2), and [Pd(C8-acac)(Me4en)]Tf2N (3) (acac = 2,4-pentanedionate, C8-acac = 3-octyl-2,4-pentanedionate, Me4en = N,N,N',N'-tetramethylethylenediamine, BuMe3en = N-butyl-N,N',N'-trimethylethylenediamin...
متن کاملAn Improvement to the Properties of GAP Binder with Energetic Ionic Liquids
Glycidyl azide polymer (GAP) is used as a binder in the propellants. Energetic ionic liquids are used as a plasticizer to correct the properties of polymer. In this study, first ionic liquid was bonded to the GAP by certain amount and then the energetic anions of nitrate (NO3) and azide (N3) were used to exchange anion. FTIR analyses confirm accurately anions exchange. DSC, viscometer and heat ...
متن کاملSulfonic acid functionalized ionic liquids for dissolution of metal oxides and solvent extraction of metal ions.
New sulfonic acid functionalized ionic liquids (SAFILs) with bis(trifluoromethylsulfonyl)imide anions were synthesized. These ionic liquids are strong Brønsted acids and can solubilize metal oxides. Water-immiscible SAFILs were used as organic phases in solvent extraction studies.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 48 17 شماره
صفحات -
تاریخ انتشار 2012